全文获取类型
收费全文 | 91篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 72篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 3篇 |
物理学 | 14篇 |
出版年
2021年 | 4篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 1篇 |
2013年 | 12篇 |
2012年 | 6篇 |
2011年 | 3篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 9篇 |
2007年 | 4篇 |
2006年 | 7篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 2篇 |
2002年 | 9篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1971年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有94条查询结果,搜索用时 781 毫秒
21.
Sagis LM Veerman C van der Linden E 《Langmuir : the ACS journal of surfaces and colloids》2004,20(3):924-927
We have determined the contour length, persistence length, bending rigidity, and critical percolation concentration for semiflexible amyloid fibrils formed from the globular proteins beta-lactoglobulin, bovine serum albumin, and ovalbumin. The persistence length was estimated using an adjusted random contact model for highly charged semiflexible chains. We have found contour lengths in the range of 50 nm to 10 microm and persistence lengths in the range of 16 nm to 1.6 microm. This wide range of contour and persistence lengths and the ease of preparation of these amyloid fibrils make them ideal model systems for the study of semiflexible polymers. 相似文献
22.
Cecile Baudin Christophe Pean Bruno Pellizzari Andree Gadelle Florence Fauvelle Jean-Claude Debouzy Jean-Pierre Dalbiez Bruno Perly 《Journal of inclusion phenomena and macrocyclic chemistry》2000,38(1-4):287-296
We report on the synthesis,characterization and ionic complexation properties ofhexakis (2-O-acetyl-3,6-anhydro)cyclomaltohexaose and hexakis (2-O-methyl-3,6-anhydro) cyclomaltohexaose usingthin-layer chromatography and Nuclear MagneticResonance spectroscopy. The selectivity towardscations depends on chemical modification of thehydroxyl groups and a very high specificity can beobtained in the case of lead for methylatedderivatives. 相似文献
23.
Mancini I Guella G Frostin M Hnawia E Laurent D Debitus C Pietra F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(35):8989-8994
Reported here is the first polyarsenic compound ever found in nature. Denominated arsenicin A, it was isolated along a bioassay-guided fractionation of the organic extract of the poecilosclerid sponge Echinochalina bargibanti collected from the north-eastern coast of New Caledonia. In defining an adamantine-type polyarsenic structure for this compound, deceptively simple NMR spectra were complemented by extensive mass spectral analysis. However, it was only the synthesis of a model compound that provided the basis to discriminate structure 4 from other spectrally compatible structures for arsenicin A; to this end, a comparative ab initio simulation of IR spectra for the natural and the synthetic compounds was decisive. Arsenicin A is endowed with potent bactericidal and fungicidal activities on human pathogenic strains. All this may revive pharmacological interest in arsenic compounds while prompting us to rethink the arsenic cycle in nature. 相似文献
24.
Background
The Kv2.1 delayed-rectifier K+ channel regulates membrane excitability in hippocampal neurons where it targets to dynamic cell surface clusters on the soma and proximal dendrites. In the past, Kv2.1 has been assumed to be absent from the axon initial segment. 相似文献25.
H.J. Koeners Cecile Schattenkerk J. Verhoeven J.H. van Boom 《Tetrahedron letters》1980,21(24):2373-2376
The synthesis of the glycopeptide Glu-Gal-Hyl-Gly, which forms an essential part of the Glomerlar Basement Membrane, is presented. The use of the levulinyl group as a protective group and the availability of the optically pure and fully-protected lactone of δ-hydroxy-L-Lysine (Hyl) will be put forward. 相似文献
26.
27.
Lensen MC Takazawa K Elemans JA Jeukens CR Christianen PC Maan JC Rowan AE Nolte RJ 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(4):831-839
The formation of micrometer-sized, highly ordered porphyrin rings on surfaces has been investigated. The porphyrin-based nanoarchitectures are formed by deposition from evaporating solutions through a surface dewetting process which can be tuned by variations in the substitution pattern of the molecules used, the coating of the surface and the conditions under which the evaporation takes place. Control over the combined self-assembly and surface dewetting results in nanorings possessing a defined internal architecture. The ordering of the molecules within the rings has been studied by a variety of microscopy techniques (TEM, AFM, fluorescence microscopy) and the exact ordering of the porphyrins within the rings has been quantified. 相似文献
28.
29.
Lylian Challier Justin Lemarchand Catherine Deanno Cecile Jauzein Giorgio Mattana Guillaume Mériguet Benjamin Rotenberg Vincent Noël 《Particle & Particle Systems Characterization》2021,38(2):2000235
Inkjet-printing is used to fabricate dielectrophoretic electrodes able to trap polystyrene (PS) microparticles as well as model planktonic cells. The possibility of rapid prototyping offered by inkjet-printing allows the rational design of microchannels with tailored electric field distributions experienced by the suspended particles, which in turn provides a handle to drive them towards target regions. Specifically, this goal is achieved using two facing substrates constituting the bottom and the top walls of the channel, with a pair of interdigitated electrodes previously patterned by inkjet-printing on each side. Influence of electrode polarization (magnitude and frequency of the input signal) is investigated both theoretically, by modeling the electric field distribution inside the channel, and experimentally using confocal fluorescence microscopy. The printed device is able to sort circulating PS particles as a function of their size, with diameters ranging from 0.5 to 5 µm, as well as to separate planktonic species according to their composition (Alexandrium minutum versus Prorocentrum micans). This work paves the way for the development of large-area, microstructured dielectrophoretic electrodes able to separate the constituents of samples at flow rates up to 150 µL mn−1. 相似文献
30.
Sainis SK Germain V Mejean CO Dufresne ER 《Langmuir : the ACS journal of surfaces and colloids》2008,24(4):1160-1164
We study the electrostatic and hydrodynamic interactions of colloidal particles in nonpolar solvents. Using blinking optical tweezers, we can extract the screening length, kappa-1, the effective surface potential, |ezeta*|, and the hydrodynamic radius, ah, in a single measurement. We apply this technique to suspensions of polystyrene and poly(methyl methacrylate) particles in hexadecane with soluble charge control agents, aerosol sodium di-2-ethylhexylsulfosuccinate (AOT) and polyisobutylene succinimide (OLOA-1200). We find that the electrostatic interactions of these particles depend sensitively on surface composition as well as on the concentration and chemistry of the charge control agent. 相似文献